Selective gas sorption in a [2+3] 'propeller' cage crystal.
نویسندگان
چکیده
A [2+3] organic cage compound based on the condensation reaction of 1,3,5-tri(4-formylphenyl)benzene with 1,5-pentanediamine was synthesized. The resulting porous molecular crystal demonstrates selective adsorption of hydrogen and carbon dioxide over nitrogen. As for porous polymer membranes, a trade-off between sorption capacity and selectivity is observed for materials in this class.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 31 شماره
صفحات -
تاریخ انتشار 2011